Journal article

Methods for Color Center Preserving Hydrogen-Termination of Diamond

DJ McCloskey, D Roberts, LVH Rodgers, Y Barsukov, ID Kaganovich, DA Simpson, NP de Leon, A Stacey, N Dontschuk

Advanced Materials Interfaces | Published : 2024

Abstract

Chemical functionalization of diamond surfaces by hydrogen is an important method for controlling the charge state of near-surface fluorescent color centers, an essential process in fabricating devices such as diamond field-effect transistors and chemical sensors, and a required first step for realizing families of more complex terminations through subsequent chemical processing. In all these cases, termination is typically achieved using hydrogen plasma sources that can etch or damage the diamond, as well as deposited materials or embedded color centers. This work explores alternative methods for lower-damage hydrogenation of diamond surfaces, specifically the annealing of diamond samples i..

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Grants

Awarded by Fusion Energy Sciences


Funding Acknowledgements

The authors acknowledge support from the Australian Research Council (ARC) through grants DP200103712, CE170100012, and FL130100119. D.J.M. acknowledged support from a University of Melbourne proof-of-concept grant and the ARC Centre of Excellence in Quantum Biotechnology through project number CE230100021. L.V.H.R. acknowledged support by the United States National Defense Science and Engineering Graduate Fellowship. In situ annealing and spectroscopy studies at Princeton were primarily supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Award No. DESC0018978, and the instrumentation development was supported by the NSF CAREER program Grant No. DMR1752047. This material is based upon work supported by U.S. Department of Energy, Office of Science, Office of Fusion Energy Sciences and Office of Basic Energy Sciences under Award No. LAB 21-2491. This work was performed in part at the Melbourne center for Nanofabrication (MCN) in the Victorian Node of the Australian National Fabrication Facility (ANFF) and also in part at RMIT University's Microscopy & Microanalysis Facility, a linked laboratory of Microscopy Australia enabled by the National Collaborative Research Infrastructure Strategy (NCRIS).